Yes, the way orderlytics works is that you promote your Createspace book and collect payment upfront. Orderlytics then places an Amazon order with your Amazon buyers account to purchase the book. Amazon then ships to your end customer.
When you set up your Orderlytics product you will use the IBSN number assigned to your book as the Retailer Product ID/SKU
Note: If you own the product and have an Amazon Sellers Pro account you can create yourself a private promotion code to purchase at a discount (up to 99% off).